We prove that the second positive Neumann eigenvalue of a bounded simply-connected planar domain of a given area does not exceed the first positive Neumann eigenvalue on a disk of half this area. The estimate is sharp and attained by a sequence of domains degenerating to a union of two identical disks. In particular, this result implies the Pólya conjecture for the second Neumann eigenvalue. The proof is based on a combination of analytic and topological arguments. As a by-product of our method we obtain an upper bound on the second eigenvalue for conformally round metrics on odd-dimensional spheres.