Skip to Main Content
Quarterly of Applied Mathematics

Quarterly of Applied Mathematics

Online ISSN 1552-4485; Print ISSN 0033-569X

   
 
 

 

Continuum mechanics of line defects in liquid crystals and liquid crystal elastomers


Authors: Amit Acharya and Kaushik Dayal
Journal: Quart. Appl. Math. 72 (2014), 33-64
MSC (2010): Primary 76A15
DOI: https://doi.org/10.1090/S0033-569X-2013-01322-X
Published electronically: November 13, 2013
MathSciNet review: 3185131
Full-text PDF Free Access

Abstract | References | Similar Articles | Additional Information

Abstract:

This paper generalizes the Ericksen-Leslie continuum model of liquid crystals to allow for dynamically evolving line defect distributions. In analogy with recent mesoscale models of dislocations, we introduce fields that represent defects in orientational and positional order through the incompatibility of the director and deformation ‘gradient’ fields. These fields have several practical implications: first, they enable a clear separation between energetics and kinetics; second, they bypass the need to explicitly track defect motion; third, they allow easy prescription of complex defect kinetics in contrast to usual regularization approaches; and finally, the conservation form of the dynamics of the defect fields has advantages for numerical schemes.

We present a dynamics of the defect fields, motivating the choice physically and geometrically. This dynamics is shown to satisfy the constraints, in this case quite restrictive, imposed by material-frame indifference. The phenomenon of permeation appears as a natural consequence of our kinematic approach. We outline the specialization of the theory to specific material classes such as nematics, cholesterics, smectics and liquid crystal elastomers. We use our approach to derive new, non-singular, finite-energy planar solutions for a family of axial wedge disclinations.


References [Enhancements On Off] (What's this?)

References
  • David R. Anderson, Donald E. Carlson, and Eliot Fried, A continuum-mechanical theory for nematic elastomers, J. Elasticity 56 (1999), no. 1, 33–58 (2000). MR 1761907, DOI https://doi.org/10.1023/A%3A1007647913363
  • A. Acharya, A model of crystal plasticity based on the theory of continuously distributed dislocations, Journal of the Mechanics and Physics of Solids 49 (2001), no. 4, 761–784.
  • Amit Acharya, Driving forces and boundary conditions in continuum dislocation mechanics, R. Soc. Lond. Proc. Ser. A Math. Phys. Eng. Sci. 459 (2003), no. 2034, 1343–1363. MR 1994263, DOI https://doi.org/10.1098/rspa.2002.1095
  • Amit Acharya, Constitutive analysis of finite deformation field dislocation mechanics, J. Mech. Phys. Solids 52 (2004), no. 2, 301–316. MR 2033975, DOI https://doi.org/10.1016/S0022-5096%2803%2900093-0
  • Amit Acharya, Jump condition for GND evolution as a constraint on slip transmission at grain boundaries, Philosophical magazine 87 (2007), no. 8, 1349–1359.
  • Amit Acharya, New inroads in an old subject: plasticity, from around the atomic to the macroscopic scale, J. Mech. Phys. Solids 58 (2010), no. 5, 766–778. MR 2642309, DOI https://doi.org/10.1016/j.jmps.2010.02.001
  • Rohan Abeyaratne and James K. Knowles, Implications of viscosity and strain-gradient effects for the kinetics of propagating phase boundaries in solids, SIAM J. Appl. Math. 51 (1991), no. 5, 1205–1221. MR 1127848, DOI https://doi.org/10.1137/0151061
  • Rohan Abeyaratne and James K. Knowles, Kinetic relations and the propagation of phase boundaries in solids, Arch. Rational Mech. Anal. 114 (1991), no. 2, 119–154. MR 1094433, DOI https://doi.org/10.1007/BF00375400
  • Amit Acharya, Karsten Matthies, and Johannes Zimmer, Travelling wave solutions for a quasilinear model of field dislocation mechanics, J. Mech. Phys. Solids 58 (2010), no. 12, 2043–2053. MR 2757690, DOI https://doi.org/10.1016/j.jmps.2010.09.008
  • Amit Acharya and Luc Tartar, On an equation from the theory of field dislocation mechanics, Boll. Unione Mat. Ital. (9) 4 (2011), no. 3, 409–444. MR 2906769
  • Ilie Bârză, On the structure of some irrotational vector fields, Gen. Math. 13 (2005), no. 1, 9–20. MR 2233634
  • J. S. Bergström and M. C. Boyce, Constitutive modeling of the large strain time-dependent behavior of elastomers, Journal of the Mechanics and Physics of Solids 46 (1998), no. 5, 931–954.
  • J. M. Ball and A. Majumdar, Nematic liquid crystals: from Maier-Saupe to a continuum theory, Oxford University Eprints archive (2009).
  • P. Bladon, M. Warner, and E. M. Terentjev, Orientational order in strained nematic networks, Macromolecules 27 (1994), no. 24, 7067–7075.
  • J. M. Ball and A. Zarnescu, Orientable and non-orientable line field models for uniaxial nematic liquid crystals, Molecular Crystals and Liquid Crystals 495 (2008), no. 1, 221–233.
  • Yi-Chao Chen and Eliot Fried, Uniaxial nematic elastomers: constitutive framework and a simple application, Proc. R. Soc. Lond. Ser. A Math. Phys. Eng. Sci. 462 (2006), no. 2068, 1295–1314. MR 2216877, DOI https://doi.org/10.1098/rspa.2005.1585
  • B. D. Coleman and M. Gurtin, Thermodynamics with internal variables, J. Chem. Phys 47 (1967), no. 2, 85–98.
  • P. Cladis and M. Kleman, Non-singular disclinations of strength S = +1 in nematics, Le Journal De Physique 33 (1972), 591–598.
  • M. Carme Calderer, Chun Liu, and Karl Voss, Smectic A liquid crystal configurations with interface defects, Math. Methods Appl. Sci. 24 (2001), no. 7, 473–489. MR 1829039, DOI https://doi.org/10.1002/mma.221
  • Bernard D. Coleman and Victor J. Mizel, Existence of caloric equations of state in thermodynamics, J. Chem. Phys. 40 (1964), 1116–1125. MR 161576, DOI https://doi.org/10.1063/1.1725257
  • Bernard D. Coleman and Walter Noll, The thermodynamics of elastic materials with heat conduction and viscosity, Arch. Rational Mech. Anal. 13 (1963), 167–178. MR 153153, DOI https://doi.org/10.1007/BF01262690
  • Kaushik Dayal and Kaushik Bhattacharya, Kinetics of phase transformations in the peridynamic formulation of continuum mechanics, J. Mech. Phys. Solids 54 (2006), no. 9, 1811–1842. MR 2244039, DOI https://doi.org/10.1016/j.jmps.2006.04.001
  • M. Doi and S. F. Edwards, The theory of polymer dynamics, Oxford University Press, USA, 1988.
  • Timothy A. Davis and Eugene C. Gartland Jr., Finite element analysis of the Landau-de Gennes minimization problem for liquid crystals, SIAM J. Numer. Anal. 35 (1998), no. 1, 336–362. MR 1618476, DOI https://doi.org/10.1137/S0036142996297448
  • P. G. de Gennes and J. Prost, The physics of liquid crystals, Oxford University Press, USA, 1995.
  • Kaushik Dayal and Richard D. James, Nonequilibrium molecular dynamics for bulk materials and nanostructures, J. Mech. Phys. Solids 58 (2010), no. 2, 145–163. MR 2649220, DOI https://doi.org/10.1016/j.jmps.2009.10.008
  • M. Doi, Molecular dynamics and rheological properties of concentrated solutions of rodlike polymers in isotropic and liquid crystalline phases, Journal of Polymer Science: Polymer Physics Edition 19 (1981), 229–243.
  • Cesare Davini and Gareth P. Parry, A complete list of invariants for defective crystals, Proc. Roy. Soc. London Ser. A 432 (1991), no. 1886, 341–365. MR 1116537, DOI https://doi.org/10.1098/rspa.1991.0021
  • A. M. Donald, A. H. Windle, and S. Hanna, Liquid crystalline polymers, Cambridge Univ Pr, 2006.
  • Weinan E, Nonlinear continuum theory of smectic-A liquid crystals, Arch. Rational Mech. Anal. 137 (1997), no. 2, 159–175. MR 1463793, DOI https://doi.org/10.1007/s002050050026
  • W. E and P. Palffy-Muhoray, Dynamics of filaments during the isotropic-smectic A phase transition, J. Nonlinear Sci. 9 (1999), no. 4, 417–437. MR 1700671, DOI https://doi.org/10.1007/s003329900075
  • J. L. Ericksen, Conservation laws for liquid crystals, Trans. Soc. Rheol. 5 (1961), 23–34. MR 158610, DOI https://doi.org/10.1122/1.548883
  • J. L. Ericksen, Liquid crystals with variable degree of orientation, Arch. Rational Mech. Anal. 113 (1990), no. 2, 97–120. MR 1079183, DOI https://doi.org/10.1007/BF00380413
  • Wendell Fleming, Functions of several variables, 2nd ed., Springer-Verlag, New York-Heidelberg, 1977. Undergraduate Texts in Mathematics. MR 0422527
  • F. C. Frank, I. Liquid crystals. On the theory of liquid crystals, Discussions of the Faraday Society 25 (1958), 19–28.
  • E. Fried and S. Sellers, Incompatible strains associated with defects in nematic elastomers, The Journal of chemical physics 124 (2006), 024908.
  • J. J. Feng, G. Sgalari, and L. G. Leal, A theory for flowing nematic polymers with orientational distortion, Journal of Rheology 44 (2000), 1085.
  • E. C. Gartland, H. Huang, O. D. Lavrentovich, P. Palffy-Muhoray, I. I. Smalyukh, T. Kosa, and B. Taheri, Electric-Field Induced Transitions in a Cholesteric Liquid-Crystal Film with Negative Dielectric Anisotropy, Journal of Computational and Theoretical Nanoscience 7 (2010), no. 4, 709–725.
  • D. J. Graziano and M. R. Mackley, Shear induced optical textures and their relaxation behaviour in thermotropic liquid crystalline polymers, Molecular Crystals and Liquid Crystals 106 (1984), no. 1, 73–93.
  • I. Haller, Elastic Constants of the Nematic Liquid Crystalline Phase of p-Methoxybenzylidene-p-n-Butylaniline (MBBA), The Journal of Chemical Physics 57 (1972), 1400.
  • W. Helfrich, Capillary flow of cholesteric and smectic liquid crystals, Physical Review Letters 23 (1969), no. 7, 372–374.
  • Rodney Hill, Aspects of invariance in solid mechanics, Advances in applied mechanics, Vol. 18, Academic Press, New York-London, 1978, pp. 1–75. MR 564892
  • M. Kleman and J. Friedel, Disclinations, dislocations, and continuous defects: a reappraisal, Rev. Modern Phys. 80 (2008), no. 1, 61–115. MR 2399129, DOI https://doi.org/10.1103/RevModPhys.80.61
  • D. Kinderlehrer, Recent developments in liquid crystal theory, Frontiers in pure and applied mathematics, North-Holland, Amsterdam, 1991, pp. 151–178. MR 1110598
  • M. Kleman and O. D. Lavrentovich, Soft Matter Physics: An Introduction, Springer Verlag, 2003.
  • D. H. Klein, L. G. Leal, C. J. García-Cervera, and H. D. Ceniceros, Three-dimensional shear-driven dynamics of polydomain textures and disclination loops in liquid crystalline polymers, Journal of Rheology 52 (2008), 837.
  • R. G. Larson, The structure and rheology of complex fluids, Oxford University Press, 1999.
  • F. M. Leslie, Some constitutive equations for liquid crystals, Arch. Rational Mech. Anal. 28 (1968), no. 4, 265–283. MR 1553506, DOI https://doi.org/10.1007/BF00251810
  • F. M. Leslie, Continuum theory for nematic liquid crystals, Contin. Mech. Thermodyn. 4 (1992), no. 3, 167–175. MR 1179949, DOI https://doi.org/10.1007/BF01130288
  • Randall J. LeVeque, Finite volume methods for hyperbolic problems, Cambridge Texts in Applied Mathematics, Cambridge University Press, Cambridge, 2002. MR 1925043
  • E. H. Lee and D. T. Liu, Finite-Strain Elastic-Plastic Theory with Application to Plane-Wave Analysis, Journal of Applied Physics 38 (1967), no. 1, 19–27.
  • Fang-Hua Lin and Chun Liu, Existence of solutions for the Ericksen-Leslie system, Arch. Ration. Mech. Anal. 154 (2000), no. 2, 135–156. MR 1784963, DOI https://doi.org/10.1007/s002050000102
  • Fang-Hua Lin and Chi-Cheung Poon, On Ericksen’s model for liquid crystals, J. Geom. Anal. 4 (1994), no. 3, 379–392. MR 1294333, DOI https://doi.org/10.1007/BF02921587
  • Chun Liu and Noel J. Walkington, Approximation of liquid crystal flows, SIAM J. Numer. Anal. 37 (2000), no. 3, 725–741. MR 1740379, DOI https://doi.org/10.1137/S0036142997327282
  • Chun Liu and Noel J. Walkington, Mixed methods for the approximation of liquid crystal flows, M2AN Math. Model. Numer. Anal. 36 (2002), no. 2, 205–222. MR 1906815, DOI https://doi.org/10.1051/m2an%3A2002010
  • Apala Majumdar and Arghir Zarnescu, Landau-De Gennes theory of nematic liquid crystals: the Oseen-Frank limit and beyond, Arch. Ration. Mech. Anal. 196 (2010), no. 1, 227–280. MR 2601074, DOI https://doi.org/10.1007/s00205-009-0249-2
  • Walter Noll, Materially uniform simple bodies with inhomogeneities, Arch. Rational Mech. Anal. 27 (1967/68), 1–32. MR 225530, DOI https://doi.org/10.1007/BF00276433
  • C. W. Oseen, The theory of liquid crystals, Transactions of the Faraday Society 29 (1933), no. 140, 883–899.
  • Prashant K. Purohit and Kaushik Bhattacharya, Dynamics of strings made of phase-transforming materials, J. Mech. Phys. Solids 51 (2003), no. 3, 393–424. MR 1949580, DOI https://doi.org/10.1016/S0022-5096%2802%2900097-2
  • R. Peierls, The size of a dislocation, Proceedings of the Physical Society 52 (1940), no. 1, 34–37.
  • S. Prager, Stress-strain relations in a suspension of dumbbells, Journal of Rheology 1 (1957), 53.
  • A. Sonnet, A. Kilian, and S. Hess, Alignment tensor versus director: Description of defects in nematic liquid crystals, Physical Review E 52 (1995), no. 1, 718–722.
  • A. M. Sonnet, P. L. Maffettone, and E. G. Virga, Continuum theory for nematic liquid crystals with tensorial order, Journal of Non-Newtonian Fluid Mechanics 119 (2004), no. 1-3, 51–59.
  • M. J. Stephen and J. P. Straley, Physics of liquid crystals, Reviews of Modern Physics 46 (1974), no. 4, 617–704.
  • O. E. Shklyaev, A. Q. Shen, and E. Fried, Evolution equation for a disclination line located between the uniaxial and isotropic phases of a nematic liquid crystal, Journal of colloid and interface science 329 (2009), no. 1, 140–152.
  • I. W. Stewart, The static and dynamic continuum theory of liquid crystals: a mathematical introduction, CRC, 2004.
  • I. W. Stewart, Dynamic theory for smectic A liquid crystals, Contin. Mech. Thermodyn. 18 (2007), no. 6, 343–360. MR 2270451, DOI https://doi.org/10.1007/s00161-006-0035-4
  • S. Shojaei-Zadeh and S. L. Anna, Role of surface anchoring and geometric confinement on focal conic textures in smectic-A liquid crystals, Langmuir 22 (2006), no. 24, 9986–9993.
  • Luc Tartar, The general theory of homogenization, Lecture Notes of the Unione Matematica Italiana, vol. 7, Springer-Verlag, Berlin; UMI, Bologna, 2009. A personalized introduction. MR 2582099
  • M. Warner and E. M. Terentjev, Liquid crystal elastomers, Oxford University Press, USA, 2007.
  • X. Yang, M. G. Forest, W. Mullins, and Q. Wang, Dynamic defect morphology and hydrodynamics of sheared nematic polymers in two space dimensions, Journal of Rheology 53 (2009), 589.
  • H. Zocher, The effect of a magnetic field on the nematic state, Transactions of the Faraday Society 29 (1933), no. 140, 945–957.

Similar Articles

Retrieve articles in Quarterly of Applied Mathematics with MSC (2010): 76A15

Retrieve articles in all journals with MSC (2010): 76A15


Additional Information

Amit Acharya
Affiliation: Civil and Environmental Engineering, Carnegie Mellon University
Email: acharyaamit@cmu.edu

Kaushik Dayal
Affiliation: Civil and Environmental Engineering, Carnegie Mellon University
Email: kaushik@cmu.edu

Keywords: Liquid crystals, disclinations, Ericksen-Leslie theory
Received by editor(s): February 23, 2012
Published electronically: November 13, 2013
Article copyright: © Copyright 2013 Brown University
The copyright for this article reverts to public domain 28 years after publication.