Comultiplications on free groups and wedges of circles

By means of the fundamental group functor, a co-H-space structure or a co-H-group structure on a wedge of circles is seen to be equivalent to a comultiplication or a cogroup structure on a free group $F$. We consider individual comultiplications on $F$ and their properties such as associativity, coloop structure, existence of inverses, etc. as well as the set of all comultiplications of $F$. For a comultiplication $m$ of $F$ we define a subset $\Delta _{m} \subseteq F$ of quasi-diagonal elements which is basic to our investigation of associativity. The subset $\Delta _{m}$ can be determined algorithmically and contains the set of diagonal elements $D_{m}$. We show that $D_{m}$ is a basis for the largest subgroup $A_{m}$ of $F$ on which $m$ is associative and that $A_{m}$ is a free factor of $F$. We also give necessary and sufficient conditions for a comultiplication $m$ on $F$ to be a coloop in terms of the Fox derivatives of $m$ with respect to a basis of $F$. In addition, we consider inverses of a comultiplication, the collection of cohomomorphisms between two free groups with comultiplication and the action of the group $\operatorname{Aut} F$ on the set of comultiplications of $F$. We give many examples to illustrate these notions. We conclude by translating these results from comultiplications on free groups to co-H-space structures on wedges of circles.